Researcher Develops 3D-Printing Technique That Leverages Oxidation as a Benefit

Prof. Changhong Ke will investigate the potential of building nanotubes into additively manufactured aluminum to mitigate the effects of corrosion. Photo courtesy of Jonathan Cohen/Binghamton University.

Prof. Changhong Ke, a faculty member at Watson College’s Department of Mechanical Engineering at Binghamton University (Binghamton, New York, USA), recently received a $150,000 grant through the National Science Foundation’s Early-concepts Grants for Exploratory Research (EAGER) program. The funding is intended to support untested but potentially transformative research ideas or approaches. 

Ke’s new research centers on a radical idea: What if there were a way to make metals stronger through oxidation? This potential breakthrough would have significant applications for industries that rely on additively manufactured metals that are more susceptible to failure in a corrosive environment and prone to increased porousness, as a result of the 3D printing process, when compared to conventionally manufactured metal. 

Ke will investigate the potential of building nanotubes into additively manufactured aluminum. He believes that microscopic structures made of boron nitride — a compound commonly used in cosmetics, pencil lead, and cement for dental applications — would make the material self-strengthening under corrosive conditions like moisture and seawater. 

“You can’t avoid oxidation, so we are trying to take advantage of it by turning it into a new, reinforcing mechanism to make the material stronger,” Ke says. “That would be something really amazing. People could try to design the materials to include these sorts of porosities or even purposely introducing structures that can be more easily oxidated because it becomes something beneficial instead of harmful to the material itself.” 

The nanotubes threaded throughout the metal are a few nanometers thick, and a few to hundreds of microns long. To see how the oxidation changes the ay that nanotubes bind to metal, a core issue in the self-strengthening mechanism, Ke and his team in the Nanomechanics Laboratory will use a force sensor to pull individual nanotubes out of the oxidized metal inside a high-resolution scanning electron microscope, which allows them to watch what is happening in real time. 

“We designed this as a sandwich structure,” Ke says. “It’s like a hot dog, with the nanotube as the meat and the metal as the bread.” 

Researchers will also test the material on a macro scale, looking at load transfer to learn more about how the oxidation affects the stiffness, strength, and toughness of the nanotube-reinforced metal. Because it’s important to understand how any self-strengthening is happening, collaborators from the University of Illinois will confirm Ke’s experimental findings through computational modeling.

“We’re hoping this will provide a new perspective to the scientific community about how we view metal oxidation in terms of future material design,” Ke says. “That could change the research landscape for these metal materials, particularly for 3D printed metal. It has so many promising applications in different areas, and it even could revitalize U.S. manufacturing competitiveness.” 

Source: BingUNews, www.binghamton.edu