A new interdisciplinary research project underway at the University of Houston (UH) (Houston, Texas, USA), funded by a $4 million grant from The Welch Foundation’s new Catalyst for Discovery Program, aims to develop innovative chemical processes to transform plastic waste into useful materials.
Houston is home to the largest concentration of petrochemicals and plastics manufacturing facilities in the world, which positions UH as a premier research institution to explore innovative recycling/upcycling technologies to help the world achieve sustainability goals and establish a circular plastics economy.
“More than 60% of plastics produced in the U.S. are polyolefins, such as polyethylene and polypropylene, which are extremely slow to biodegrade,” says Megan Robertson, project director and professor of chemical engineering at UH’s Cullen College of Engineering.
According to the World Economic Forum, the U.S. only recycled about 6% of the 40 million tons (80 billion lbs.) of plastic waste it generated in 2021. Around the world, about 400 million tons (800 billion lbs.) of plastic waste is produced each year. Much of it ends up in landfills, oceans, and natural habitats, negatively impacting the environment, human health, and wildlife.
“We’re tackling a complex problem that needs a diverse team with a wide range of expertise in polymer synthesis, polymer physics, and materials science,” says Olafs Daugulis, the Robert A. Welch Chair of Chemistry at UH. “The chemists on the team will lead the development of unique polyolefins with new material properties and functions, while the chemical engineers will study their physical behavior and properties, such as strength and adhesion. This knowledge is crucial for creating new materials that can be recycled and reused more effectively.”
Joining Robertson and Daugulis on the research team are Ramanan Krishnamoorti and Alamgir Karim from the William A. Brookshire Department of Chemical and Biomolecular Engineering at the Cullen College of Engineering, and Maurice Brookhart and Brad Carrow from the Department of Chemistry at the College of Natural Sciences and Mathematics. This project will be conducted in collaboration with UH’s Energy Transition Institute, which is built on three core pillars: carbon management, hydrogen, and circular plastics.
The team will tackle the challenges with polyolefins through a three-pronged approach:
1) Value-added recycling: Recycling mixed plastics is a notoriously difficult and costly process. The researchers are developing a game-changing solution by creating modular “compatibilizers” — special polymers or molecules that can blend different types of plastic waste that otherwise do not want to mix. The compatibilizers can be designed to work with the diverse plastic waste streams that may enter a recycling facility and can change on a day-to-day basis. This innovation will streamline the recycling process, making it more efficient and economical.
2) Upcycling plastics: The goal of traditional recycling is often to produce an item similar to the original, like turning a water bottle into another water bottle. However, diverting this plastic from landfills in the long run would involve recycling it not just once, but many times in succession. In this project, the researchers seek to upcycle polyolefin waste into durable thermoset materials. These polymers can be used in long-lasting applications, such as insulation, coatings, or automotive products, where they could be used for a decade or longer. Upcycling the waste in this manner thus could have a long-term impact on keeping the waste out of landfills and the environment. Ultimately, these thermosets could also be recycled and the team is investigating innovative ways to do this.
3) Enabling circular reuse: Polyolefins are notoriously stable polymers. While this is a favorable aspect for their use in products, they degrade in the environment at a slow rate. The team is bringing new functionality into the polymers through incorporating chemical groups that will accelerate their degradation. This will enable efficient deconstruction, separation, purification, and re-formation of the polymers from the degraded plastics.
“We’re providing a multi-pronged approach to managing polyolefin waste, each enabled by catalytic strategies for bringing new chemical groups into the polymers,” says Robertson, who added that preliminary work has already been conducted on all three aspects of the project to demonstrate feasibility. “This is a big opportunity and, now that we have the resources, we are really excited to take these projects to the next level.”
Source: University of Houston, www.uh.edu.